Book Reviews

Book Reviews of: Birchall, J. Rediscovering the Cooperative Advantage: Poverty Reduction through Self-help Geneva: International Labour Office, 2003; Steinnert, H. and Pilgram, A. (eds.) Welfare Policy From Below: Struggles Against Social Exclusion in Europe Aldershot, UK: Ashgate, 2003Teaching/Communication/Extension/Profession,

LANDSAT-4 horizon scanner performance evaluation

Representative data spans covering a little more than a year since the LANDSAT-4 launch were analyzed to evaluate the flight performance of the satellite's horizon scanner. High frequency noise was filtered out by 128-point averaging. The effects of Earth oblateness and spacecraft altitude variations are modeled, and residual systematic errors are analyzed. A model for the predicted radiance effects is compared with the flight data and deficiencies in the radiance effects modeling are noted. Correction coefficients are provided for a finite Fourier series representation of the systematic errors in the data. Analysis of the seasonal dependence of the coefficients indicates the effects of some early mission problems with the reference attitudes which were computed by the onboard computer using star trackers and gyro data. The effects of sun and moon interference, unexplained anomalies in the data, and sensor noise characteristics and their power spectrum are described. The variability of full orbit data averages is shown. Plots of the sensor data for all the available data spans are included

Essential and inessential elements of a standard basis

In this paper we introduce the concept of inessential element of a standard basis of I, where I is any homogeneous ideal of a polynomial ring. An inessential element is, roughly speaking, a form of the basis whose omission produces an ideal having the same saturation of I; it becomes useless in any dehomogenization of I with respect to a linear form. We study the properties of the basis linked to the presence of inessential elements and give some examples.Comment: 15 page

Determination of Equilibrium Constants for the Reaction between Acetone and HO_2 Using Infrared Kinetic Spectroscopy

The reaction between the hydroperoxy radical, HO_2, and acetone may play an important role in acetone removal and the budget of HO_x radicals in the upper troposphere. We measured the equilibrium constants of this reaction over the temperature range of 215–272 K at an overall pressure of 100 Torr using a flow tube apparatus and laser flash photolysis to produce HO_2. The HO_2 concentration was monitored as a function of time by near-IR diode laser wavelength modulation spectroscopy. The resulting [HO_2] decay curves in the presence of acetone are characterized by an immediate decrease in initial [HO_2] followed by subsequent decay. These curves are interpreted as a rapid (<100 μs) equilibrium reaction between acetone and the HO_2 radical that occurs on time scales faster than the time resolution of the apparatus, followed by subsequent reactions. This separation of time scales between the initial equilibrium and ensuing reactions enabled the determination of the equilibrium constant with values ranging from 4.0 × 10^(–16) to 7.7 × 10^(–1)8 cm^3 molecule^(–1) for T = 215–272 K. Thermodynamic parameters for the reaction determined from a second-law fit of our van’t Hoff plot were Δ_(r)H°_(245) = −35.4 ± 2.0 kJ mol^(–1) and Δ_(r)S°_(245) = −88.2 ± 8.5 J mol^(–1) K^(–1). Recent ab initio calculations predict that the reaction proceeds through a prereactive hydrogen-bonded molecular complex (HO_2–acetone) with subsequent isomerization to a hydroxy–peroxy radical, 2-hydroxyisopropylperoxy (2-HIPP). The calculations differ greatly in the energetics of the complex and the peroxy radical, as well as the transition state for isomerization, leading to significant differences in their predictions of the extent of this reaction at tropospheric temperatures. The current results are consistent with equilibrium formation of the hydrogen-bonded molecular complex on a short time scale (100 μs). Formation of the hydrogen-bonded complex will have a negligible impact on the atmosphere. However, the complex could subsequently isomerize to form the 2-HIPP radical on longer time scales. Further experimental studies are needed to assess the ultimate impact of the reaction of HO_2 and acetone on the atmosphere

Conceptual design of a manned orbital transfer vehicle

With the advent of the manned space station, man now requires a spacecraft based on the space station with the ability to deploy, recover, and repair satellites quickly and economically. Such a craft would prolong and enhance the life and performance of many satellites. A basic design was developed for an orbital tansfer vehicle (OTV). The basic design criteria are discussed. The design of the OTV and systems were researched in the following areas: avionics, crew systems, electrical power systems, environmental control/life support systems, navigation and orbital maneuvers, propulsion systems, reaction control systems (RCS), servicing systems, and structures. The basic concepts in each of the areas are summarized

Two designs for an orbital transfer vehicle

The Orbital Transfer Vehicle (OTV) and systems were researched in the following areas: avionics, crew systems, electrical power systems, environmental control/life support systems, navigation and orbital maneuvers, propulsion systems, reaction control systems (RCS), servicing systems, and structures